Pablo Sanz Monreal

@article{MERCADER2026136698,

title = {Intensifying synthetic natural gas production by functionalization of a NiFe/γ-Al2O3 catalyst with alkaline and alkaline-earth materials},

author = {V. D. Mercader and P. Sanz-Monreal and P. Durán and P. Aragüés-Aldea and E. Francés and J. Herguido and J. A. Peña},

url = {https://www.sciencedirect.com/science/article/pii/S0016236125024238},

doi = {https://doi.org/10.1016/j.fuel.2025.136698},

issn = {0016-2361},

year  = {2026},

date = {2026-01-01},

journal = {Fuel},

volume = {406},

pages = {136698},

abstract = {This study demonstrates the influence of the functionalization method (Mechanical Mixture -MM- and Dual Function Materials -DFM-) of two CO2 adsorbent species (Na and Ca) in a catalytic fixed-bed reactor for CO2 methanation. The experiments consisted of cycles beginning with a CO2 adsorption stage followed by a methanation stage (with H2), interspersed with or without inert purge periods. The greatest enhancement in methane generation was observed in experiments with a mechanical mixture (MM) of NiFe/γ-Al2O3 catalyst and Na2O/γ-Al2O3. The methane production capacity was tested over a temperature range comprised between 200 and 400 °C, with values over 380 μmol/g obtained under moderate conditions (350 °C and pCO2 = 0.12 bar) and selectivity to methane close to 100 %. Since the ultimate goal is the methanation of the CO2 present in a biogas (without removing CH4), the potential effect of the presence of methane during the CO2 adsorption stages was also investigated. To achieve this task, a feed stream representative of a sweetened biogas coming from the anaerobic decomposition of municipal solid waste (MSW) (70 %v CH4 and 30 %v CO2) was used. The results showed no adverse effects along the successive cycles, paving the way to the use of these solids for biogas upgrading. On the other hand, the catalyst did not show a significant loss of activity after several hours of repetitive adsorption-methanation cycles.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}

@article{SANZMONREAL2025107871,

title = {Techno-economic assessment of a plant for the upgrading of MSW biogas to synthetic natural gas by thermocatalytic methanation},

author = {P. Sanz-Monreal and V. D. Mercader and P. Aragüés-Aldea and P. Durán and E. Francés and J. Herguido and J. A. Peña},

url = {https://www.sciencedirect.com/science/article/pii/S096195342500282X},

doi = {https://doi.org/10.1016/j.biombioe.2025.107871},

issn = {0961-9534},

year  = {2025},

date = {2025-01-01},

journal = {Biomass and Bioenergy},

volume = {198},

pages = {107871},

abstract = {This study evaluates the techno-economic feasibility of a plant designed to produce synthetic natural gas (SNG) from biogas through direct catalytic methanation. The proposed facility is simulated with Aspen Plus® v14, using a comprehensive approach that covers the entire process, from biogas pretreatment to the production of the final product. The installation aims to contribute to the development of Power-to-Gas (Power-to-Methane) strategy for decarbonization. The plant, to be located in northeastern Spain, operates at an industrial scale with a production capacity of approximately 1100 Nm3/h of SNG, obtained from a 1425 Nm3/h biogas plant. The process includes five main stages to meet Spanish gas quality standards for grid injection: desulfurization, using amines for sulfur removal; electrolysis, for the generation of renewable hydrogen; thermocatalytic methanation, which combines CO2 from the biogas with hydrogen to enrich the methane content; dehydration, to meet SNG moisture specifications; and cogeneration, intended for the joint production of electricity and steam to meet the plant's energy demands. A detailed analysis of investment costs (CAPEX) and operational expenses (OPEX) is conducted, identifying the key factors influencing the project's profitability. The economic assessment indicates a total capital investment of 21.83 M€ and operational expenses nearly 8 M€ annually. The profitability threshold for the base scenario is estimated at 91.75 €/MWh, exceeding the 2023 natural gas market average in the Iberic peninsula (39.11 €/MWh), highlighting the current economic challenges of SNG production.},

keywords = {},

pubstate = {published},

tppubtype = {article}

}