{"id":3769,"date":"2023-09-01T14:00:30","date_gmt":"2023-09-01T12:00:30","guid":{"rendered":"https:\/\/creg-dev.i3a.es\/?p=3769"},"modified":"2025-07-30T12:45:04","modified_gmt":"2025-07-30T10:45:04","slug":"javier-herguido","status":"publish","type":"post","link":"https:\/\/creg.i3a.es\/es\/javier-herguido\/","title":{"rendered":"Javier Herguido"},"content":{"rendered":"<div id=\"pl-gb3769-6a4bd80bca401\"  class=\"panel-layout wp-block-siteorigin-panels-layout-block\" ><div id=\"pg-gb3769-6a4bd80bca401-0\"  class=\"panel-grid panel-has-style\" ><div class=\"siteorigin-panels-stretch panel-row-style panel-row-style-for-gb3769-6a4bd80bca401-0\" data-stretch-type=\"full-width-stretch\" ><div id=\"pgc-gb3769-6a4bd80bca401-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-gb3769-6a4bd80bca401-0-0-0\" class=\"so-panel widget widget_sow-hero panel-first-child panel-last-child\" data-index=\"0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-hero so-widget-sow-hero-default-93415d0e2dbf-3769 so-widget-fittext-wrapper\"\n\t\t\t data-fit-text-compressor=\"0.85\"\n\t\t>\t\t\t\t<div class=\"sow-slider-base\" style=\"display: none\" tabindex=\"0\">\n\t\t\t\t\t<ul\n\t\t\t\t\tclass=\"sow-slider-images\"\n\t\t\t\t\tdata-settings=\"{&quot;pagination&quot;:true,&quot;speed&quot;:800,&quot;timeout&quot;:8000,&quot;paused&quot;:false,&quot;pause_on_hover&quot;:false,&quot;swipe&quot;:true,&quot;nav_always_show_desktop&quot;:&quot;&quot;,&quot;nav_always_show_mobile&quot;:&quot;&quot;,&quot;breakpoint&quot;:&quot;780px&quot;,&quot;unmute&quot;:false,&quot;anchor&quot;:null}\"\n\t\t\t\t\t\t\t\t\t\tdata-anchor-id=\"\"\n\t\t\t\t>\t\t<li class=\"sow-slider-image\" style=\"visibility: visible;;background-color: #1e73be\" >\n\t\t\t\t\t<div class=\"sow-slider-image-container\">\n\t\t\t<div class=\"sow-slider-image-wrapper\">\n\t\t\t\t<h3 style=\"text-align: center\"><a href=\"..\/people\/\">Investigadores<\/a><\/h3>\n<h1 style=\"text-align: center\"><strong>Javier Herguido<br \/>\n<\/strong><\/h1>\n\t\t\t<\/div>\n\t\t<\/div>\n\t\t\t\t<\/li>\n\t\t<\/ul>\t\t\t\t<ol class=\"sow-slider-pagination\">\n\t\t\t\t\t\t\t\t\t\t\t<li><a href=\"#\" data-goto=\"0\" aria-label=\"mostrar diapositiva 1\"><\/a><\/li>\n\t\t\t\t\t\t\t\t\t<\/ol>\n\n\t\t\t\t<div class=\"sow-slide-nav sow-slide-nav-next\">\n\t\t\t\t\t<a href=\"#\" data-goto=\"next\" aria-label=\"diapositiva siguiente\" data-action=\"next\">\n\t\t\t\t\t\t<em class=\"sow-sld-icon-thin-right\"><\/em>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\n\t\t\t\t<div class=\"sow-slide-nav sow-slide-nav-prev\">\n\t\t\t\t\t<a href=\"#\" data-goto=\"previous\" aria-label=\"diapositiva anterior\" data-action=\"prev\">\n\t\t\t\t\t\t<em class=\"sow-sld-icon-thin-left\"><\/em>\n\t\t\t\t\t<\/a>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div><\/div><\/div><\/div><\/div><\/div><\/div>\n\n<div id=\"pl-gb3769-6a4bd80bcad9e\"  class=\"panel-layout wp-block-siteorigin-panels-layout-block\" ><div id=\"pg-gb3769-6a4bd80bcad9e-0\"  class=\"panel-grid 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sizes=\"auto, (max-width: 37px) 100vw, 37px\" \/>\t\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t<div class=\"sow-image-grid-image\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/twitter.com\/HerguidoJavier\"\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\ttarget=\"_blank\" \t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\trel=\"noopener noreferrer\" \t\t\t\t\t\t\t\t\t\t\t>\n\t\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"36\" height=\"37\" src=\"https:\/\/creg.i3a.es\/wp-content\/uploads\/2023\/09\/logo-black-e1693998108290.png\" class=\"sow-image-grid-image_html\" alt=\"\" title=\"\" srcset=\"https:\/\/creg.i3a.es\/wp-content\/uploads\/2023\/09\/logo-black-e1693998108290.png 36w, https:\/\/creg.i3a.es\/wp-content\/uploads\/2023\/09\/logo-black-e1693998108290-12x12.png 12w\" sizes=\"auto, (max-width: 36px) 100vw, 36px\" \/>\t\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t<div class=\"sow-image-grid-image\">\n\t\t\t\t\t\t\t\t\t\t\t\t\t<a href=\"https:\/\/scholar.google.es\/citations?user=FXksYDcAAAAJ&#038;hl=es\"\n\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\ttarget=\"_blank\" \t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\t\trel=\"noopener noreferrer\" \t\t\t\t\t\t\t\t\t\t\t>\n\t\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" width=\"37\" height=\"37\" src=\"https:\/\/creg.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar.png\" class=\"sow-image-grid-image_html\" alt=\"\" title=\"\" srcset=\"https:\/\/creg.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar.png 37w, https:\/\/creg.i3a.es\/wp-content\/uploads\/2020\/10\/google-scholar-12x12.png 12w\" sizes=\"auto, (max-width: 37px) 100vw, 37px\" \/>\t\t\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t\t\t\t\t\t\t<\/div>\n\t\t\t<\/div>\n<\/div><\/div><\/div><div id=\"panel-gb3769-6a4bd80bcad9e-0-1-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<blockquote>\n<p><strong>Tel\u00e9fono:<\/strong> +34 976 762 393<\/p>\n<p><strong>Email:<\/strong> <a href=\"mailto:jhergui@unizar.es\">jhergui@unizar.es<\/a><\/p>\n<p><strong>Direcci\u00f3n:<\/strong> Office 4.2.9 c\/Mariano Esquillor SN Edificio I+D+i, I3A, 50018, Zaragoza (Spain)<\/p>\n<p><strong>Sideral:<\/strong> <a href=\"https:\/\/sideral.unizar.es\/sideral\/CV\/francisco-javier-herguido-huerta\" target=\"_blank\" rel=\"noopener\">Ver el perfil (CV)<\/a><\/p>\n<\/blockquote>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div>\n\n<div id=\"pl-gb3769-6a4bd80bcc901\"  class=\"panel-layout wp-block-siteorigin-panels-layout-block\" ><div id=\"pg-gb3769-6a4bd80bcc901-0\"  class=\"panel-grid panel-has-style\" ><div class=\"panel-row-style panel-row-style-for-gb3769-6a4bd80bcc901-0\" ><div id=\"pgc-gb3769-6a4bd80bcc901-0-0\"  class=\"panel-grid-cell\" ><div id=\"panel-gb3769-6a4bd80bcc901-0-0-0\" class=\"so-panel widget widget_sow-headline panel-first-child\" data-index=\"0\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-headline so-widget-sow-headline-default-244eb6bef45a-3769\"\n\t\t\t\n\t\t><div class=\"sow-headline-container\">\n\t\t\t\t\t\t\t<h5 class=\"sow-headline\">\n\t\t\t\t\t\tSOBRE M\u00cd\t\t\t\t\t\t<\/h5>\n\t\t\t\t\t\t\t\t\t\t\t<div class=\"decoration\">\n\t\t\t\t\t\t<div class=\"decoration-inside\"><\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n<\/div><\/div><div id=\"panel-gb3769-6a4bd80bcc901-0-0-1\" class=\"so-panel widget widget_sow-editor panel-last-child\" data-index=\"1\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-editor so-widget-sow-editor-base\"\n\t\t\t\n\t\t>\n<div class=\"siteorigin-widget-tinymce textwidget\">\n\t<p style=\"text-align: justify;\">Javier Herguido es Catedr\u00e1tico de Ingenier\u00eda Qu\u00edmica en la Escuela de Ingenier\u00eda y Arquitectura (EINA) de la Universidad de Zaragoza (Unizar), desde 2007. Licenciado. y M.Sc. en Qu\u00edmica, especialidad industrial (1987) y Doctor en Ciencias \u2013 Programa de Ingenier\u00eda Qu\u00edmica (1991). Premio Extraordinario de Doctorado de Unizar. En 1993 titular de la c\u00e1tedra 'Chaire H\u00e9lioparc' en el Centro Tecnol\u00f3gico 'H\u00e9lioparc Pau-Pyr\u00e9n\u00e9es' (Francia). Profesor invitado en varios centros de investigaci\u00f3n y universidades: \u2018Laboratoire de Physico-Chimie Mol\u00e9culaire\u2019 CNRS-Francia, Universidad PUCP-Per\u00fa, Universidad Nacional de Cuenca-Ecuador.<\/p>\n<p style=\"text-align: justify;\">Actualmente es Director del Departamento de Ingenier\u00eda Qu\u00edmica y Tecnolog\u00edas del Medio Ambiente \u2013 Unizar (desde 2016), y Secretario de la Sociedad Espa\u00f1ola de Cat\u00e1lisis (SECAT).<\/p>\n<p style=\"text-align: justify;\" class=\"translation-block\">En su actividad investigadora es miembro del Grupo de Cat\u00e1lisis e Ingenier\u00eda de Reactores (CREG) y del Instituto Universitario de Investigaciones en Ingenier\u00eda de Arag\u00f3n (I3A). Su investigaci\u00f3n presente se centra en el \u00e1rea de Ingenier\u00eda de Reactores Qu\u00edmicos, incluyendo::<br>\n a) Reactores de lecho fluidizado con zonas oxidantes y reductoras para procesos de oxidaci\u00f3n selectiva y para deshidrogenaciones catal\u00edticas.:<br>\nb) Tecnolog\u00edas del hidr\u00f3geno: sus actuales esfuerzos de investigaci\u00f3n se dedican a campos relacionados con la producci\u00f3n y\/o purificaci\u00f3n de hidr\u00f3geno de diversas fuentes, la utilizaci\u00f3n del hidr\u00f3geno en procesos Power to Gas como la metanaci\u00f3n de CO<sub>2<\/sub> y procesos Power to Liquid como la producci\u00f3n de metanol, DME, etc.:<br> \nc) Intensificaci\u00f3n de procesos, incluido el uso de reactores de membrana.<\/p>\n<p style=\"text-align: justify;\">Ha participado en 43 proyectos de investigaci\u00f3n, en gran parte como investigador principal. Su producci\u00f3n cient\u00edfica incluye: 120 art\u00edculos (contando 2 revisiones por invitaci\u00f3n) en revistas indexadas en JCR como AIChEJ, Appl. Catal., Cat. Today, CEJ., CES, I&amp;ECR, Int. J. Hydrogen Energy, J. Catal., J. Power Sources, Powder Tech., Studies Surf. Sci. Catal., entre otros; m\u00e1s de 370 presentaciones en congresos\/conferencias cient\u00edficas; 3 patentes; y el libro \u201cIngenier\u00eda de Reactores\u201d (1999, Ed. S\u00edntesis, Madrid). Es Premio Fundaci\u00f3n 3M a la Innovaci\u00f3n (2004), en su categor\u00eda de Medio Ambiente.  Ha dirigido 14 tesis doctorales. \n\u00cdndice H: 35 (G-Scholar, 3790 citas), 30 (Scopus, 2760 citas) -octubre 2023-<\/p>\n<p>Orcid: <a href=\"https:\/\/orcid.org\/0000-0003-1940-9597\">https:\/\/orcid.org\/0000-0003-1940-9597<\/a><\/p>\n<p>Scopus: <a href=\"https:\/\/www.scopus.com\/authid\/detail.uri?authorId=57195414034\">https:\/\/www.scopus.com\/authid\/detail.uri?authorId=57195414034<\/a><\/p>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><div id=\"pg-gb3769-6a4bd80bcc901-1\"  class=\"panel-grid panel-has-style\" ><div class=\"panel-row-style panel-row-style-for-gb3769-6a4bd80bcc901-1\" ><div id=\"pgc-gb3769-6a4bd80bcc901-1-0\"  class=\"panel-grid-cell\" ><div id=\"panel-gb3769-6a4bd80bcc901-1-0-0\" class=\"so-panel widget widget_sow-headline panel-first-child\" data-index=\"2\" ><div\n\t\t\t\n\t\t\tclass=\"so-widget-sow-headline so-widget-sow-headline-default-244eb6bef45a-3769\"\n\t\t\t\n\t\t><div class=\"sow-headline-container\">\n\t\t\t\t\t\t\t<h5 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class=\"teachpress_publication_list\"><h3 class=\"tp_h3\" id=\"tp_h3_2026\">2026<\/h3><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Mercader, V. D.;  Sanz-Monreal, P.;  Dur\u00e1n, P.;  Arag\u00fc\u00e9s-Aldea, P.;  Franc\u00e9s, E.;  Herguido, J.;  Pe\u00f1a, J. A.<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('3063','tp_links')\" style=\"cursor:pointer;\">Intensifying synthetic natural gas production by functionalization of a NiFe\/\u03b3-Al2O3 catalyst with alkaline and alkaline-earth materials<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Fuel, <\/span><span class=\"tp_pub_additional_volume\">vol. 406, <\/span><span class=\"tp_pub_additional_pages\">pp. 136698, <\/span><span class=\"tp_pub_additional_year\">2026<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 0016-2361<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_3063\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3063','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_3063\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3063','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_3063\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3063','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_3063\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{MERCADER2026136698,<br \/>\r\ntitle = {Intensifying synthetic natural gas production by functionalization of a NiFe\/\u03b3-Al2O3 catalyst with alkaline and alkaline-earth materials},<br \/>\r\nauthor = {V. D. Mercader and P. Sanz-Monreal and P. Dur\u00e1n and P. Arag\u00fc\u00e9s-Aldea and E. Franc\u00e9s and J. Herguido and J. A. Pe\u00f1a},<br \/>\r\nurl = {https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016236125024238},<br \/>\r\ndoi = {https:\/\/doi.org\/10.1016\/j.fuel.2025.136698},<br \/>\r\nissn = {0016-2361},<br \/>\r\nyear  = {2026},<br \/>\r\ndate = {2026-01-01},<br \/>\r\njournal = {Fuel},<br \/>\r\nvolume = {406},<br \/>\r\npages = {136698},<br \/>\r\nabstract = {This study demonstrates the influence of the functionalization method (Mechanical Mixture -MM- and Dual Function Materials -DFM-) of two CO2 adsorbent species (Na and Ca) in a catalytic fixed-bed reactor for CO2 methanation. The experiments consisted of cycles beginning with a CO2 adsorption stage followed by a methanation stage (with H2), interspersed with or without inert purge periods. The greatest enhancement in methane generation was observed in experiments with a mechanical mixture (MM) of NiFe\/\u03b3-Al2O3 catalyst and Na2O\/\u03b3-Al2O3. The methane production capacity was tested over a temperature range comprised between 200 and 400\u00a0\u00b0C, with values over 380\u00a0\u03bcmol\/g obtained under moderate conditions (350\u00a0\u00b0C and pCO2\u00a0=\u00a00.12\u00a0bar) and selectivity to methane close to 100\u00a0%. Since the ultimate goal is the methanation of the CO2 present in a biogas (without removing CH4), the potential effect of the presence of methane during the CO2 adsorption stages was also investigated. To achieve this task, a feed stream representative of a sweetened biogas coming from the anaerobic decomposition of municipal solid waste (MSW) (70\u00a0%v CH4 and 30\u00a0%v CO2) was used. The results showed no adverse effects along the successive cycles, paving the way to the use of these solids for biogas upgrading. On the other hand, the catalyst did not show a significant loss of activity after several hours of repetitive adsorption-methanation cycles.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3063','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_3063\" style=\"display:none;\"><div class=\"tp_abstract_entry\">This study demonstrates the influence of the functionalization method (Mechanical Mixture -MM- and Dual Function Materials -DFM-) of two CO2 adsorbent species (Na and Ca) in a catalytic fixed-bed reactor for CO2 methanation. The experiments consisted of cycles beginning with a CO2 adsorption stage followed by a methanation stage (with H2), interspersed with or without inert purge periods. The greatest enhancement in methane generation was observed in experiments with a mechanical mixture (MM) of NiFe\/\u03b3-Al2O3 catalyst and Na2O\/\u03b3-Al2O3. The methane production capacity was tested over a temperature range comprised between 200 and 400\u00a0\u00b0C, with values over 380\u00a0\u03bcmol\/g obtained under moderate conditions (350\u00a0\u00b0C and pCO2\u00a0=\u00a00.12\u00a0bar) and selectivity to methane close to 100\u00a0%. Since the ultimate goal is the methanation of the CO2 present in a biogas (without removing CH4), the potential effect of the presence of methane during the CO2 adsorption stages was also investigated. To achieve this task, a feed stream representative of a sweetened biogas coming from the anaerobic decomposition of municipal solid waste (MSW) (70\u00a0%v CH4 and 30\u00a0%v CO2) was used. The results showed no adverse effects along the successive cycles, paving the way to the use of these solids for biogas upgrading. On the other hand, the catalyst did not show a significant loss of activity after several hours of repetitive adsorption-methanation cycles.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3063','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_3063\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016236125024238\" title=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016236125024238\" target=\"_blank\">https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016236125024238<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/https:\/\/doi.org\/10.1016\/j.fuel.2025.136698\" title=\"DOI de seguimiento:https:\/\/doi.org\/10.1016\/j.fuel.2025.136698\" target=\"_blank\">doi:https:\/\/doi.org\/10.1016\/j.fuel.2025.136698<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3063','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Gonz\u00e1lez-Pizarro, R.;  Calero-Berrocal, R.;  Lasobras, J.;  Renda, S.;  Rodr\u00edguez-Pardo, M. R.;  Soler, J.;  Men\u00e9ndez, M.;  Herguido, J.<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('3064','tp_links')\" style=\"cursor:pointer;\">Tuning e-fuel selectivity in sorption-enhanced CO2 hydrogenation over In2O3\/ZrO2: The effect of LTA and FAU zeolites<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Fuel, <\/span><span class=\"tp_pub_additional_volume\">vol. 406, <\/span><span class=\"tp_pub_additional_pages\">pp. 136974, <\/span><span class=\"tp_pub_additional_year\">2026<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 0016-2361<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_3064\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3064','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_3064\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3064','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_3064\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3064','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_3064\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{GONZALEZPIZARRO2026136974,<br \/>\r\ntitle = {Tuning e-fuel selectivity in sorption-enhanced CO2 hydrogenation over In2O3\/ZrO2: The effect of LTA and FAU zeolites},<br \/>\r\nauthor = {R. Gonz\u00e1lez-Pizarro and R. Calero-Berrocal and J. Lasobras and S. Renda and M. R. Rodr\u00edguez-Pardo and J. Soler and M. Men\u00e9ndez and J. Herguido},<br \/>\r\nurl = {https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016236125026997},<br \/>\r\ndoi = {https:\/\/doi.org\/10.1016\/j.fuel.2025.136974},<br \/>\r\nissn = {0016-2361},<br \/>\r\nyear  = {2026},<br \/>\r\ndate = {2026-01-01},<br \/>\r\njournal = {Fuel},<br \/>\r\nvolume = {406},<br \/>\r\npages = {136974},<br \/>\r\nabstract = {The e-fuels synthesis via CO2 hydrogenation and the Sorption Enhanced Reaction technology are captivating strategies for CO2 utilization and the integration of renewable energy sources. This study focuses on enhancing the conversion of CO2 over an In2O3\/ZrO2 catalyst by incorporating LTA zeolites (3A and 4A) and a FAU zeolite (13X). Key operational parameters, such as temperature (T), Gas Hour Space Velocity (GHSV), type of zeolite, and Zeolite: Catalyst mass ratio (Z\/C), were systematically varied. LTA zeolites (3A and 4A) provided the highest CO2 conversions. The introduction of a water-adsorbing solid into the reactor significantly altered the products yield and selectivity. While the selectivity towards CH4, CH3OH, and C2H6O appeared to lay on the type of zeolite, the selectivity towards CO remained unaffected. Zeolite 3A demonstrated the greatest enhancement in selectivity towards CH4 and CH3OH, whereas the synthesis of C2H6O was favored by zeolites 4A and 13X. The Zeolite:Catalyst mass ratio also played a crucial role in process performance, influencing both CO2 conversion and product selectivity. Increasing this ratio improved CO2 conversion and reduced CO selectivity under all operating conditions, while CH4 selectivity increased. However, the selectivity toward CH3OH and C2H6O exhibited an anomalous and complementary behavior. While a maximum was observed for DME, a minimum was registered in methanol production, suggesting a dependency of the dehydration reaction kinetics on the amount of water produced during the reaction.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3064','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_3064\" style=\"display:none;\"><div class=\"tp_abstract_entry\">The e-fuels synthesis via CO2 hydrogenation and the Sorption Enhanced Reaction technology are captivating strategies for CO2 utilization and the integration of renewable energy sources. This study focuses on enhancing the conversion of CO2 over an In2O3\/ZrO2 catalyst by incorporating LTA zeolites (3A and 4A) and a FAU zeolite (13X). Key operational parameters, such as temperature (T), Gas Hour Space Velocity (GHSV), type of zeolite, and Zeolite: Catalyst mass ratio (Z\/C), were systematically varied. LTA zeolites (3A and 4A) provided the highest CO2 conversions. The introduction of a water-adsorbing solid into the reactor significantly altered the products yield and selectivity. While the selectivity towards CH4, CH3OH, and C2H6O appeared to lay on the type of zeolite, the selectivity towards CO remained unaffected. Zeolite 3A demonstrated the greatest enhancement in selectivity towards CH4 and CH3OH, whereas the synthesis of C2H6O was favored by zeolites 4A and 13X. The Zeolite:Catalyst mass ratio also played a crucial role in process performance, influencing both CO2 conversion and product selectivity. Increasing this ratio improved CO2 conversion and reduced CO selectivity under all operating conditions, while CH4 selectivity increased. However, the selectivity toward CH3OH and C2H6O exhibited an anomalous and complementary behavior. While a maximum was observed for DME, a minimum was registered in methanol production, suggesting a dependency of the dehydration reaction kinetics on the amount of water produced during the reaction.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3064','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_3064\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016236125026997\" title=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016236125026997\" target=\"_blank\">https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0016236125026997<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/https:\/\/doi.org\/10.1016\/j.fuel.2025.136974\" title=\"DOI de seguimiento:https:\/\/doi.org\/10.1016\/j.fuel.2025.136974\" target=\"_blank\">doi:https:\/\/doi.org\/10.1016\/j.fuel.2025.136974<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3064','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Gonz\u00e1lez-Pizarro, R.;  Renda, S.;  Lasobras, J.;  Soler, J.;  Men\u00e9ndez, M.;  Herguido, J.<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('3066','tp_links')\" style=\"cursor:pointer;\">Low loading copper-based catalysts for effective CO2 hydrogenation to methanol<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Fuel, <\/span><span class=\"tp_pub_additional_volume\">vol. 408, <\/span><span class=\"tp_pub_additional_pages\">pp. 137642, <\/span><span class=\"tp_pub_additional_year\">2026<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 0016-2361<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_3066\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3066','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_3066\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3066','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_3066\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3066','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_3066\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{GONZALEZPIZARRO2026137642,<br \/>\r\ntitle = {Low loading copper-based catalysts for effective CO2 hydrogenation to methanol},<br \/>\r\nauthor = {R. Gonz\u00e1lez-Pizarro and S. Renda and J. Lasobras and J. Soler and M. Men\u00e9ndez and J. Herguido},<br \/>\r\nurl = {https:\/\/www.sciencedirect.com\/science\/article\/pii\/S001623612503368X},<br \/>\r\ndoi = {https:\/\/doi.org\/10.1016\/j.fuel.2025.137642},<br \/>\r\nissn = {0016-2361},<br \/>\r\nyear  = {2026},<br \/>\r\ndate = {2026-01-01},<br \/>\r\njournal = {Fuel},<br \/>\r\nvolume = {408},<br \/>\r\npages = {137642},<br \/>\r\nabstract = {Methanol synthesis via CO2 hydrogenation is an emerging Power-to-Liquid (PtL) technology aimed to accelerate the energy transition and the defossilization of key sectors, particularly maritime transport. This study focuses on the study of low loading formulations, to minimize the catalyst cost. Key operational variables including temperature (T), Weight Hourly Space Velocity (WHSV), copper and zinc loadings, and aging state were systematically varied. An overall active phase loading of 10\u00a0%wt emerged as optimal. Within this total loading, a 5\u00a0%wtCu-5\u00a0%wtZn\/ZrO2 catalysts delivered higher methanol productivity than 10\u00a0%wtCu\/ZrO2; however, the bimetallic catalysts showed pronounced deactivation under water-rich atmospheres, establishing 10\u00a0%wtCu\/ZrO2 as the most promising catalysts. Operating temperature and WHSV exerted a strong, synergistic influence on CH3OH formation; in particular, increasing WHSV shifted the reaction away from thermodynamic control and boosted methanol synthesis. Finally, the catalytic performance of these low-loading catalysts was benchmarked against high-copper-loading methanol catalysts reported in the literature by critically compare their activities as a function of the residence time (\u03c4) calculated at reaction conditions. This assessment revealed that the proposed formulation is highly competitive when compared to most conventional formulation, with a maximum methanol space time yield (STYCH3OH) of 3.9 gCH3OH gCu-1\u00a0h-1. This comparison confirms that the catalysts proposed in this study could offer a remarkably more efficient use of the active phase than the conventional high-copper-loading catalysts.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3066','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_3066\" style=\"display:none;\"><div class=\"tp_abstract_entry\">Methanol synthesis via CO2 hydrogenation is an emerging Power-to-Liquid (PtL) technology aimed to accelerate the energy transition and the defossilization of key sectors, particularly maritime transport. This study focuses on the study of low loading formulations, to minimize the catalyst cost. Key operational variables including temperature (T), Weight Hourly Space Velocity (WHSV), copper and zinc loadings, and aging state were systematically varied. An overall active phase loading of 10\u00a0%wt emerged as optimal. Within this total loading, a 5\u00a0%wtCu-5\u00a0%wtZn\/ZrO2 catalysts delivered higher methanol productivity than 10\u00a0%wtCu\/ZrO2; however, the bimetallic catalysts showed pronounced deactivation under water-rich atmospheres, establishing 10\u00a0%wtCu\/ZrO2 as the most promising catalysts. Operating temperature and WHSV exerted a strong, synergistic influence on CH3OH formation; in particular, increasing WHSV shifted the reaction away from thermodynamic control and boosted methanol synthesis. Finally, the catalytic performance of these low-loading catalysts was benchmarked against high-copper-loading methanol catalysts reported in the literature by critically compare their activities as a function of the residence time (\u03c4) calculated at reaction conditions. This assessment revealed that the proposed formulation is highly competitive when compared to most conventional formulation, with a maximum methanol space time yield (STYCH3OH) of 3.9 gCH3OH gCu-1\u00a0h-1. This comparison confirms that the catalysts proposed in this study could offer a remarkably more efficient use of the active phase than the conventional high-copper-loading catalysts.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3066','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_3066\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S001623612503368X\" title=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S001623612503368X\" target=\"_blank\">https:\/\/www.sciencedirect.com\/science\/article\/pii\/S001623612503368X<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/https:\/\/doi.org\/10.1016\/j.fuel.2025.137642\" title=\"DOI de seguimiento:https:\/\/doi.org\/10.1016\/j.fuel.2025.137642\" target=\"_blank\">doi:https:\/\/doi.org\/10.1016\/j.fuel.2025.137642<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3066','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Gonz\u00e1lez-Pizarro, R.;  Lasobras, J.;  Renda, S.;  Soler, J.;  Men\u00e9ndez, M.;  Herguido, J.<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('3067','tp_links')\" style=\"cursor:pointer;\">Overcoming thermodynamic limitations of the low-temperature reverse water-gas shift in a sorption-enhanced fluidized bed reactor with continuous sorbent feeding and separation (SEFBR\u00a0+\u00a0CSF)<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Separation and Purification Technology, <\/span><span class=\"tp_pub_additional_volume\">vol. 404, <\/span><span class=\"tp_pub_additional_pages\">pp. 138902, <\/span><span class=\"tp_pub_additional_year\">2026<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 1383-5866<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_3067\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3067','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_3067\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3067','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_3067\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3067','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_3067\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{GONZALEZPIZARRO2026138902,<br \/>\r\ntitle = {Overcoming thermodynamic limitations of the low-temperature reverse water-gas shift in a sorption-enhanced fluidized bed reactor with continuous sorbent feeding and separation (SEFBR\u00a0+\u00a0CSF)},<br \/>\r\nauthor = {R. Gonz\u00e1lez-Pizarro and J. Lasobras and S. Renda and J. Soler and M. Men\u00e9ndez and J. Herguido},<br \/>\r\nurl = {https:\/\/www.sciencedirect.com\/science\/article\/pii\/S1383586626021684},<br \/>\r\ndoi = {https:\/\/doi.org\/10.1016\/j.seppur.2026.138902},<br \/>\r\nissn = {1383-5866},<br \/>\r\nyear  = {2026},<br \/>\r\ndate = {2026-01-01},<br \/>\r\njournal = {Separation and Purification Technology},<br \/>\r\nvolume = {404},<br \/>\r\npages = {138902},<br \/>\r\nabstract = {Abstract <br \/>\r\nThis work presents a novel approach for intensifying the reverse water gas shift (rWGS) reaction by integrating an advanced fluidized-bed reactor design with a continuous solid sorbent feeding\/separation strategy. The proposed Sorption Enhanced Fluidized Bed Reactor combined with Continuous Sorbent Feeding and Separation (SEFBR\u00a0+\u00a0CSF) enables continuous operation while maintaining the intensification effect traditionally associated with temporal-limited sorption-enhanced processes. This configuration externalizes the regeneration of the water-adsorbing zeolite, which is continuously and selectively withdrawn from the reactor in a partially or fully saturated state and replaced with regenerated material, thereby sustaining the sorption capacity throughout operation. Process intensification was experimentally demonstrated in the SEFBR\u00a0+\u00a0CSF configuration, which achieved CO yields significantly higher than those obtained in the conventional fluidized-bed reactor (cFBR). During the interval in which continuous sorbent feeding was applied, CO production surpassed the thermodynamic equilibrium limit at operating temperatures between 260 and 300\u00a0\u00b0C. When compared with literature data under similar conditions, the proposed system exhibited superior CO yields, particularly in the low-temperature regime where conventional LT-rWGS performance is typically limited. Overall, the SEFBR\u00a0+\u00a0CSF system represents a promising pathway for continuous sorption-enhanced operation, providing improved efficiency and enabling the process to exceed the equilibrium constraints of the LT-rWGS reaction.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3067','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_3067\" style=\"display:none;\"><div class=\"tp_abstract_entry\">Abstract <br \/>\r\nThis work presents a novel approach for intensifying the reverse water gas shift (rWGS) reaction by integrating an advanced fluidized-bed reactor design with a continuous solid sorbent feeding\/separation strategy. The proposed Sorption Enhanced Fluidized Bed Reactor combined with Continuous Sorbent Feeding and Separation (SEFBR\u00a0+\u00a0CSF) enables continuous operation while maintaining the intensification effect traditionally associated with temporal-limited sorption-enhanced processes. This configuration externalizes the regeneration of the water-adsorbing zeolite, which is continuously and selectively withdrawn from the reactor in a partially or fully saturated state and replaced with regenerated material, thereby sustaining the sorption capacity throughout operation. Process intensification was experimentally demonstrated in the SEFBR\u00a0+\u00a0CSF configuration, which achieved CO yields significantly higher than those obtained in the conventional fluidized-bed reactor (cFBR). During the interval in which continuous sorbent feeding was applied, CO production surpassed the thermodynamic equilibrium limit at operating temperatures between 260 and 300\u00a0\u00b0C. When compared with literature data under similar conditions, the proposed system exhibited superior CO yields, particularly in the low-temperature regime where conventional LT-rWGS performance is typically limited. Overall, the SEFBR\u00a0+\u00a0CSF system represents a promising pathway for continuous sorption-enhanced operation, providing improved efficiency and enabling the process to exceed the equilibrium constraints of the LT-rWGS reaction.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3067','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_3067\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S1383586626021684\" title=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S1383586626021684\" target=\"_blank\">https:\/\/www.sciencedirect.com\/science\/article\/pii\/S1383586626021684<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/https:\/\/doi.org\/10.1016\/j.seppur.2026.138902\" title=\"DOI de seguimiento:https:\/\/doi.org\/10.1016\/j.seppur.2026.138902\" target=\"_blank\">doi:https:\/\/doi.org\/10.1016\/j.seppur.2026.138902<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3067','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><div class=\"tp_publication tp_publication_article\"><div class=\"tp_pub_info\"><p class=\"tp_pub_author\"> Arag\u00fc\u00e9s-Aldea, P.;  Dur\u00e1n, P.;  Mercader, V. D.;  Renda, S.;  Franc\u00e9s, E.;  Pe\u00f1a, J. A.;  Herguido, J.<\/p><p class=\"tp_pub_title\"><a class=\"tp_title_link\" onclick=\"teachpress_pub_showhide('3069','tp_links')\" style=\"cursor:pointer;\">Packed-bed membrane reactors as a strategy for selective CO2 methanation<\/a> <span class=\"tp_pub_type tp_  article\">Art\u00edculo de revista<\/span> <\/p><p class=\"tp_pub_additional\"><span class=\"tp_pub_additional_in\">En: <\/span><span class=\"tp_pub_additional_journal\">Catalysis Today, <\/span><span class=\"tp_pub_additional_volume\">vol. 476, <\/span><span class=\"tp_pub_additional_pages\">pp. 115899, <\/span><span class=\"tp_pub_additional_year\">2026<\/span>, <span class=\"tp_pub_additional_issn\">ISSN: 0920-5861<\/span>.<\/p><p class=\"tp_pub_menu\"><span class=\"tp_abstract_link\"><a id=\"tp_abstract_sh_3069\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3069','tp_abstract')\" title=\"Mostrar resumen\" style=\"cursor:pointer;\">Resumen<\/a><\/span> | <span class=\"tp_resource_link\"><a id=\"tp_links_sh_3069\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3069','tp_links')\" title=\"Mostrar enlaces y recursos\" style=\"cursor:pointer;\">Enlaces<\/a><\/span> | <span class=\"tp_bibtex_link\"><a id=\"tp_bibtex_sh_3069\" class=\"tp_show\" onclick=\"teachpress_pub_showhide('3069','tp_bibtex')\" title=\"Mostrar entrada BibTeX \" style=\"cursor:pointer;\">BibTeX<\/a><\/span><\/p><div class=\"tp_bibtex\" id=\"tp_bibtex_3069\" style=\"display:none;\"><div class=\"tp_bibtex_entry\"><pre>@article{ARAGUESALDEA2026115899,<br \/>\r\ntitle = {Packed-bed membrane reactors as a strategy for selective CO2 methanation},<br \/>\r\nauthor = {P. Arag\u00fc\u00e9s-Aldea and P. Dur\u00e1n and V. D. Mercader and S. Renda and E. Franc\u00e9s and J. A. Pe\u00f1a and J. Herguido},<br \/>\r\nurl = {https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0920586126002233},<br \/>\r\ndoi = {https:\/\/doi.org\/10.1016\/j.cattod.2026.115899},<br \/>\r\nissn = {0920-5861},<br \/>\r\nyear  = {2026},<br \/>\r\ndate = {2026-01-01},<br \/>\r\njournal = {Catalysis Today},<br \/>\r\nvolume = {476},<br \/>\r\npages = {115899},<br \/>\r\nabstract = {CO2 methanation represents a key route within Power-to-X strategies for converting captured carbon into synthetic natural gas. However, its efficiency is limited by thermodynamic constraints, heat management issues, and undesired CO formation due to the reverse water\u2013gas shift reaction. In this work, a novel packed-bed membrane reactor (PBMR), conceived as an evolution of the polytropic packed-bed reactor (PPBR), is proposed and experimentally validated for selective CO2 methanation. The reactor enables distributed reactant feeding through a porous membrane wall, allowing enhanced control over local reaction environments along the catalytic bed. A Ni\u2013Fe\/Al2O3 catalyst was employed and tested under various operating conditions, including different weight hourly space velocities (WHSV) and feeding configurations (conventional, co-current, and counter-current). The influence of distributing either H2 or CO2 was systematically investigated in terms of CO2 conversion, temperature profiles, and CO selectivity. While distributed configurations did not improve overall CO2 conversion compared to conventional operation, they significantly affected selectivity. In particular, CO2-distributed feeding consistently reduced CO selectivity under iso-conversion conditions, achieving up to a 40% decrease in the most favorable case. This significant reduction highlights the effectiveness of spatial reactant management in driving the reaction pathway toward methane. Overall, these results underline the critical role of reactor design in overcoming selectivity limitations and demonstrate the potential of membrane-assisted distributed feeding as a process intensification strategy for CO2 methanation.},<br \/>\r\nkeywords = {},<br \/>\r\npubstate = {published},<br \/>\r\ntppubtype = {article}<br \/>\r\n}<br \/>\r\n<\/pre><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3069','tp_bibtex')\">Cerrar<\/a><\/p><\/div><div class=\"tp_abstract\" id=\"tp_abstract_3069\" style=\"display:none;\"><div class=\"tp_abstract_entry\">CO2 methanation represents a key route within Power-to-X strategies for converting captured carbon into synthetic natural gas. However, its efficiency is limited by thermodynamic constraints, heat management issues, and undesired CO formation due to the reverse water\u2013gas shift reaction. In this work, a novel packed-bed membrane reactor (PBMR), conceived as an evolution of the polytropic packed-bed reactor (PPBR), is proposed and experimentally validated for selective CO2 methanation. The reactor enables distributed reactant feeding through a porous membrane wall, allowing enhanced control over local reaction environments along the catalytic bed. A Ni\u2013Fe\/Al2O3 catalyst was employed and tested under various operating conditions, including different weight hourly space velocities (WHSV) and feeding configurations (conventional, co-current, and counter-current). The influence of distributing either H2 or CO2 was systematically investigated in terms of CO2 conversion, temperature profiles, and CO selectivity. While distributed configurations did not improve overall CO2 conversion compared to conventional operation, they significantly affected selectivity. In particular, CO2-distributed feeding consistently reduced CO selectivity under iso-conversion conditions, achieving up to a 40% decrease in the most favorable case. This significant reduction highlights the effectiveness of spatial reactant management in driving the reaction pathway toward methane. Overall, these results underline the critical role of reactor design in overcoming selectivity limitations and demonstrate the potential of membrane-assisted distributed feeding as a process intensification strategy for CO2 methanation.<\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3069','tp_abstract')\">Cerrar<\/a><\/p><\/div><div class=\"tp_links\" id=\"tp_links_3069\" style=\"display:none;\"><div class=\"tp_links_entry\"><ul class=\"tp_pub_list\"><li><i class=\"fas fa-globe\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0920586126002233\" title=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0920586126002233\" target=\"_blank\">https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0920586126002233<\/a><\/li><li><i class=\"ai ai-doi\"><\/i><a class=\"tp_pub_list\" href=\"https:\/\/dx.doi.org\/https:\/\/doi.org\/10.1016\/j.cattod.2026.115899\" title=\"DOI de seguimiento:https:\/\/doi.org\/10.1016\/j.cattod.2026.115899\" target=\"_blank\">doi:https:\/\/doi.org\/10.1016\/j.cattod.2026.115899<\/a><\/li><\/ul><\/div><p class=\"tp_close_menu\"><a class=\"tp_close\" onclick=\"teachpress_pub_showhide('3069','tp_links')\">Cerrar<\/a><\/p><\/div><\/div><\/div><\/div><div class=\"tablenav\"><div class=\"tablenav-pages\"><span class=\"displaying-num\">154 registros<\/span> <a class=\"page-numbers button disabled\">&laquo;<\/a> <a class=\"page-numbers button disabled\">&lsaquo;<\/a> 1 de 31 <a href=\"https:\/\/creg.i3a.es\/es\/javier-herguido\/?limit=2&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"p\u00e1gina siguiente\" class=\"page-numbers button\">&rsaquo;<\/a> <a href=\"https:\/\/creg.i3a.es\/es\/javier-herguido\/?limit=31&amp;tgid=&amp;yr=&amp;type=&amp;usr=&amp;auth=&amp;tsr=#tppubs\" title=\"\u00faltima p\u00e1gina\" class=\"page-numbers button\">&raquo;<\/a> <\/div><\/div><\/div>\n<\/div>\n<\/div><\/div><\/div><\/div><\/div><\/div>\n\n\n<p><\/p>","protected":false},"excerpt":{"rendered":"","protected":false},"author":3,"featured_media":4742,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[238,239],"tags":[],"class_list":["post-3769","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-permanent-members","category-team"],"_links":{"self":[{"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/posts\/3769","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/comments?post=3769"}],"version-history":[{"count":15,"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/posts\/3769\/revisions"}],"predecessor-version":[{"id":5444,"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/posts\/3769\/revisions\/5444"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/media\/4742"}],"wp:attachment":[{"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/media?parent=3769"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/categories?post=3769"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/creg.i3a.es\/es\/wp-json\/wp\/v2\/tags?post=3769"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}